The deuterium/hydrogen isotopic ratio, D/H, is one of the keys to understand the origin of water on terrestrial bodies within the Solar System and its evolution over time in their atmospheres.
In the atmosphere of Mars, this D/H ratio is on average 5 to 6 times higher than what is found on Earth (Earth oceans serve as a reference with the Vienna Standard Mean Ocean Water, VSMOW). Although Martian water is present only in very low quantities (100 ppmv on average), its high deuterium enrichment points to a wetter past for the red planet, which is supported by various geological indicators (valleys, ancient lakes, shorelines). To understand this result and how the water has escaped from Mars' atmosphere, the study of HDO – the main source of changes in the D/H ratio on the planet – and its annual cycle appears essential, particularly regarding its seasonal behavior in the upper atmosphere where water vapor can be photodissociated and then ejected.
The Mars PCM (Planetary Climate Model) simulates the Martian atmosphere physical, chemical and dynamical processes; including water ice cloud-related phenomena, such as condensation, which play a significant role in the relative behavior of HDO. This model, coupled with observations and data from ACS (Atmospheric Chemistry Suite), has shed light on the HDO cycle in recent years. However, differences still exist between the model results and the observations. This is particularly the case for the vertical distribution of water vapor in the upper atmosphere. Some improvements to the MPCM, e.g. dust, water clouds and gravity waves are provided, and their effects are studied and discussed. One of them is the implementation of a more realistic dust particles size distribution in the model. These improvements provide a more realistic HDO cycle as well as a more reliable source of comparison with the ACS observations. The goal is to further understand the nature and origin of the high deuterium enrichment on the red planet.